Synthesis and Component Analysis of an Iron (Iii) Oxalate...

Experiments 4A-C: Synthesis and Component Analysis of an Iron (III) Oxalate Complex My Name TA, Section B## Work Performed on 10/23, 10/30, 11/4, 200# Report due Tuesday, November ##, 200# 1. Abstract This experiment initially involved the synthesis of an iron (III) oxalate complex with the general formula Kw[Fex(C2O4)y] ·zH2O. The variables x, y, and z were determined through the duration of the entire experiment. From 1.2000g of Fe(NH4)2(SO4)2 were synthesized 1.1###g of K3[FeIII(C2O4)3] ·3H2O, owing for a percentage yield of 74.###%. A percentage yield of 11#.##% was also calculated, had the final product been K[FeIII(C2O4)2] ·2H2O. This value was rejected because experimental errors are never to exceed theoretical values,†¦show more content†¦The redox components occur in pairs, with one species (the reductant) giving up its electron(s) to be taken up by the other species (the oxidant). 4A involves the synthesis of an iron (III) oxalate complex. The iron is first presented in its Fe2+ form, so it must first be oxidized to Fe3+ before the oxalate ion will bind readily to it. Hydrogen peroxide is the oxidant of choice: 2Fe2+ (aq) + H2O2 (l) + 2H+ (aq) 2Fe3+ (aq) + 2H2O (l), in acidic solution. (1) The oxalate ion is then free to coordinate to the Fe3+ ion, forming a complex of Fe(C2O4). The oxalate ion is the conjugate base of the weak oxalic acid, H2C2O4. In lab, careful attention is paid to the maintenance of the H2C2O4-C2O42- equilibrium, as only the oxalate ion is capable of coordinating. This is done through the addition of H2C2O4 and the soluble K2C2O4 – only the oxalate anion is of concern: (2) The complex may then be synthesized – the general reaction equation is: aFe(NH4)2(SO4)2 ·6H2O + bK+ + cC2O42- + dH2C2O4 eK3[Fe3+(C2O4)3] ·3H2O (3) The complex is then precipitated out and rendered into a crystalline form with ice (decreased temperature results in decreased solubility) and ethanol (a polar solvent; the nonpolar target product will have limited solubility in ethanol because of the violation of the like-dissolves-like rule). The most likely synthesis products areShow MoreRelatedSynthesis and Component Analysis of an Iron (Iii) Oxalate Complex7868 Words   |  32 PagesExperiments 4A-C: Synthesis and Component Analysis of an Iron (III) Oxalate Complex My Name TA, Section B## Work Performed on 10/23, 10/30, 11/4, 200# Report due Tuesday, November ##, 200# 1. Abstract This experiment initially involved the synthesis of an iron (III) oxalate complex with the general formula Kw[Fex(C2O4)y] ·zH2O. The variables x, y, and z were determined through the duration of the entire experiment. From 1.2000g of Fe(NH4)2(SO4)2 were synthesized 1.1###g of K3[FeIII(C2O4)3] ·3H2ORead MoreIons in Our Daily Life2554 Words   |  11 Pagesis a common mechanism exploited by natural and artificial biocides, including the ion channels gramicidin and amphotericin (a fungicide). Inorganic dissolved ions are a component of total dissolved solids, an indicator of water quality in the world. Chemistry Notation Denoting the charged state Equivalent notations for an iron atom (Fe) that lost two electrons. When writing the chemical formula for an ion, its net charge is written in superscript immediately after the chemical structure for theRead MoreThe Extraction of Pectin from Orange Peels13647 Words   |  55 Pagesin the extraction step and varied volumetric ratio of the Ethanol in the precipitation. The results obtained showed that methanol extraction of oil as a pre-treatment gave a higher yield of pectin than using hydrochloric acid on the raw peel. The analysis carried out on the extracted pectin showed that pectin from post-methanol pre-treatment residue have a dark brown colour, with density of 0.133 g/cm3 and a yield of 16.06% while that without methanol pre-treatment have a greenish yellow colour, 0 Synthesis and Component Analysis of an Iron (Iii) Oxalate... Experiments 4A-C: Synthesis and Component Analysis of an Iron (III) Oxalate Complex My Name TA, Section B## Work Performed on 10/23, 10/30, 11/4, 200# Report due Tuesday, November ##, 200# 1. Abstract This experiment initially involved the synthesis of an iron (III) oxalate complex with the general formula Kw[Fex(C2O4)y] ·zH2O. The variables x, y, and z were determined through the duration of the entire experiment. From 1.2000g of Fe(NH4)2(SO4)2 were synthesized 1.1###g of K3[FeIII(C2O4)3] ·3H2O, owing for a percentage yield of 74.###%. A percentage yield of 11#.##% was also calculated, had the final product been K[FeIII(C2O4)2] ·2H2O. This value was rejected because experimental errors are never to exceed theoretical values,†¦show more content†¦Experiment 4C utilized Spectrophotometry to determine the iron content in the iron (III) oxalate complex. The results were combined with findings from 4A and 4B to determine the empirical formula and percentage yield of the compound synthesized in 4A. Spectrophotometry is a routine laboratory test that has the added advantage of being able to analyze multiple samples in a short amount of time. The sample to be tested absorbs a certain amount of electromagnetic radiation from a source, and the amount absorbed is related to the concentration of a species in solution—or more specifically, the concentration (c) and the path length (b). the ratio of intensity of light entering the cell (I0) and leaving the cell (I) are related by Beer’s Law. The transmittance (T) represents the fraction of the original radiant energy that passes through, or is transmitted, to the other wise of the cell. These terms are related by the equation: ï £ «1ï £ ¶ ï £ « I. ï £ ¶ ï £ «1ï £ ¶ ï £ « I. ï £ ¶ lnï £ ¬ ï £ · = lnï £ ¬ ï £ · = kbc or logï £ ¬ ï £ · = logï £ ¬ ï £ · = ÃŽ µbc (5) ï £ ­T ï £ ¸ ï £ ­Iï £ ¸ ï £ ­T ï £ ¸ ï £ ­Iï £ ¸ The term I0/I is renamed absorbance where A=ÃŽ µbc with A=log(1/T). The conversion between absorbance ï £ « 100 ï £ ¶ and percent transmittance is given by A = logï £ ¬ ï £ · . The most efficient way of determining ï £ ­ %T ï £ ¸ concentration is to prepare a set of standard solutions of known concentration,Show MoreRelatedSynthesis and Component Analysis of an Iron (Iii) Oxalate Complex7868 Words   |  32 PagesExperiments 4A-C: Synthesis and Component Analysis of an Iron (III) Oxalate Complex My Name TA, Section B## Work Performed on 10/23, 10/30, 11/4, 200# Report due Tuesday, November ##, 200# 1. Abstract This experiment initially involved the synthesis of an iron (III) oxalate complex with the general formula Kw[Fex(C2O4)y] ·zH2O. The variables x, y, and z were determined through the duration of the entire experiment. From 1.2000g of Fe(NH4)2(SO4)2 were synthesized 1.1###g of K3[FeIII(C2O4)3] ·3H2ORead MoreIons in Our Daily Life2554 Words   |  11 Pagesis a common mechanism exploited by natural and artificial biocides, including the ion channels gramicidin and amphotericin (a fungicide). Inorganic dissolved ions are a component of total dissolved solids, an indicator of water quality in the world. Chemistry Notation Denoting the charged state Equivalent notations for an iron atom (Fe) that lost two electrons. When writing the chemical formula for an ion, its net charge is written in superscript immediately after the chemical structure for theRead MoreThe Extraction of Pectin from Orange Peels13647 Words   |  55 Pagesin the extraction step and varied volumetric ratio of the Ethanol in the precipitation. The results obtained showed that methanol extraction of oil as a pre-treatment gave a higher yield of pectin than using hydrochloric acid on the raw peel. The analysis carried out on the extracted pectin showed that pectin from post-methanol pre-treatment residue have a dark brown colour, with density of 0.133 g/cm3 and a yield of 16.06% while that without methanol pre-treatment have a greenish yellow colour, 0